报告题目:sp3碳-氢氧化氟化反应研究
报告人:夏纪宝 研究员、博导
中科院“百人计划”研究员
报告人单位:中科院兰州化学物理研究所,羰基合成与选择氧化国家重点实验室,
报告时间:2017年3月14日(星期二)15:00
报告地点:新校区303多媒体教室
组织单位:437必赢会员中心 科技处
生态环境相关高分子材料教育部重点实验室
甘肃省高分子材料重点实验室
甘肃省生物电化学与环境分析重点实验室
甘肃省电化学技术与纳米器件工程实验室
夏纪宝研究员简介:
夏纪宝,研究员,博士生导师,中科院“百人计划”, 2010年 中科院上海有机化学研究所博士毕业, 2010.9 – 2015.3 在得州大学西南医学中心做博士后工作,2015.3 – 中科院兰州化学物理研究所,研究员 J. Am. Chem. Soc.、Chem. Commun、ChemCatChem等国际著名期刊发表多篇学术论文
一、 荣誉奖励
2010上海有机所GSK 奖学金
2015中科院“百人计划”A类
二、代表论著
17. Zhu, D.-Y.; Chen, P.; Xia, J.-B. “Synthesis of Planar Chiral Ferrocenes by Transition-Metal-Catalyzed Enantioselective C–H Activation” ChemCatChem, 2016, 8, 68-73.
16. Xia, J.-B.; You, S.-L. „„C–C Bond Formation byDouble C–H Bond Activation‟‟, in Science of Synthesis, Yu, J.-Q., Ed, Thieme, Stuttgart, 2015, 115-136.
15. Xia, J.-B.; Zhu, C.; Chen, C. “Visible Light-Promoted Metal-Free sp3-C–H Fluorination” Chem. Commun. 2014, 50, 11701-11704.
14. Xia, J.-B.; Ma, Y.; Chen, C. “Vanadium-Catalyzed C(sp3)–H Fluorination Reactions” Org. Chem. Front. 2014, 1, 468-472.
13. Zhu, C.; Xia, J.-B.; Chen, C. “A Simple Method for the Electrophilic Cyanation of Secondary Amines” Org. Lett. 2014, 16, 247-250.
12. Zhu, C.; Xia, J.-B.; Chen, C. “Vanadium-Catalyzed Oxidative Strecker Reaction: α-C–H Cyanation of para-Methoxyphenyl (PMP)-Protected Primary Amines” Tetrahedron Lett.2014, 55, 232-234.
11. Xia, J.-B.; Zhu, C.; Chen, C. “Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination” J. Am. Chem. Soc.2013, 135, 17494-17500.
Highlighted in Synfacts 2014, 10, 85.
10. Xia, J.-B.; Cormier, W. K.; Chen, C. “A Highly Selective Vanadium Catalyst forBenzylic C–H Oxidation” Chem. Sci.2012, 3, 2240-2245.
9. Liu, W.-B.; Xia, J.-B.; You, S.-L. “Iridium-Catalyzed Asymmetirc Allylic Substitutions” Top. Organomet. Chem. 2012, 38, 155-208.
8. Xia, J.-B.; Liu, W.-B.; Wang, T.-M.; You, S.-L. “Enantioselective Synthesis of 3-Azabicyclo[4.1.0]heptanes and 3-Azabicyclo[3.2.0]heptanes viaIr-Catalyzed Asymmetric Allylic Amination of N-Tosyl Propynylamine and Pt-Catalyzed Cycloisomerization Reaction” Chem. Eur. J.2010, 16, 6442-6446.
Highlighted in Synfacts 2010, 8, 909.
7. You, S.-L.; Xia, J.-B.; „„Palladium-Catalyzed Aryl–Aryl Bond Formation through Double C–H Activation‟‟ Top. Curr. Chem. 2010, 292, 165-194.
6. Xia, J.-B.; Jamison, T. F.; You, S.-L. „„Monodentate Chiral Ferrocenyl Ligands‟‟, in Chiral Ferrocenes in Asymmetric Catalysis: Synthesis and Applications, Dai, L.-X., Hou, X.-L., Eds, WILEY-VCH, Weinheim, 2010, pp. 55-71.
5. Xia, J.-B.; Zhuo, C.-X.; You, S.-L. “Synthesis of Cyclopropane-containing Building Blocks viaIr-Catalyzed Enantioselective Allylic Substitution Reaction” Chin. J. Chem. 2010, 28, 1525-1528.
4. Xia, J.-B.; You, S.-L. „„Synthesis of 3-Haloindolizines by Copper(II) Halides Mediated Direct Functionalization of Indolizines‟‟ Org. Lett. 2009, 11, 1187-1190.
3. Xia, J.-B.; Wang, X.-Q.; You, S.-L.„„Synthesis of Biindolizines through Highly Regioselective Palladium-Catalyzed C–H Functionalization‟‟ J. Org. Chem. 2009, 74, 456-458.
2. Wang, X.-Q.; Xia, J.-B.; Dai, X.-Y.; You, S.-L.„„Preparation of Ferrocenyl Imidazolines using Bis(triphenyl)oxodiphosphonium Trifluoromethansulfonate” Sci. China Chem.2009, 52,1331-1336.
1. Xia, J.-B.; You, S.-L.„„Carbon–CarbonBond Formation through Double sp2 C–H Activations: Synthesis of Ferrocenyl Oxazoline Derivatives‟‟ Organometallics 2007, 26, 4869-4871
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